Difference between revisions of "Tape Casting"
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[[File:Proceq tape caster.jpg|thumb|Another doctor-blade tape caster with exchangable reservoirs and doctor-blades. Additionally, a heating plate can be useful during drying.]] | [[File:Proceq tape caster.jpg|thumb|Another doctor-blade tape caster with exchangable reservoirs and doctor-blades. Additionally, a heating plate can be useful during drying.]] | ||
| − | Continuous as well as discontinuous tapes can be prepared with lab-scale tape casters. For continuous tapes, guide rollers and rollers with the carrier substrate are needed. If discontinuous tapes are produced, carrier substrate sheets can be used likewise | + | Continuous as well as discontinuous tapes can be prepared with lab-scale tape casters. For continuous tapes, guide rollers and rollers with the carrier substrate are needed. If discontinuous tapes are produced, carrier substrate sheets can be used likewise. |
[[File:Schematic doctor blading.png|thumb|Schematic of the doctor-blade tape casting technique. The slip is poured in a reservoir and cast on a carrier. The doctor-blade height defines the green sheet's thickness.<ref>[https://doi.org/10.1007/978-94-011-0531-6_5] Mistler, R.E. (1995), The principles of tape casting and tape casting applications. In: Terpstra, R.A., Pex, P.P.A.C., de Vries, A.H. (eds) Ceramic Processing. Springer, Dordrecht.</ref>]] | [[File:Schematic doctor blading.png|thumb|Schematic of the doctor-blade tape casting technique. The slip is poured in a reservoir and cast on a carrier. The doctor-blade height defines the green sheet's thickness.<ref>[https://doi.org/10.1007/978-94-011-0531-6_5] Mistler, R.E. (1995), The principles of tape casting and tape casting applications. In: Terpstra, R.A., Pex, P.P.A.C., de Vries, A.H. (eds) Ceramic Processing. Springer, Dordrecht.</ref>]] | ||
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=== Reservoir === | === Reservoir === | ||
=== Doctor-blade === | === Doctor-blade === | ||
| + | Other | ||
| + | variables that come into play include reservoir depth, speed of carrier | ||
| + | movement, viscosity of the slip, and shape of the doctor blade (to | ||
| + | name just a few). | ||
| + | |||
=== Drying chamber === | === Drying chamber === | ||
== Process of tape casting == | == Process of tape casting == | ||
=== Slip delivery === | === Slip delivery === | ||
| + | |||
| + | After mixing the slip system, air can be trapped within the slip. To remove remaining air bubbles and promote smooth and homogeneous green tapes without defects, a de-airing step is required. Putting the slip under vacuum will help to remove air. It needs to be noted that too high vacuum tends to let evaporate solvent. This will unbalance the weight ratios of the slip and change its rheological behavior. Subsequent to de airing the slip will be poured into the reservoir of the machine. Additional sieves can be used to prevent e.g. milling balls from falling into the reservoir. Before starting to cast the slip is supposed to be distributed in the reservoir. | ||
| + | |||
=== Casting === | === Casting === | ||
| + | |||
| + | The doctor-blade gap defines the wet thickness of the tape being cast. Either the substrate is stationary or the doctor-blade. The speed is supposed to be set in the range of 0.7 - 1 m/min. | ||
| + | |||
=== Drying === | === Drying === | ||
=== Quality assessment === | === Quality assessment === | ||
Revision as of 16:42, 27 October 2022
One of the most well-known and used method to manufacture multilayered ceramic components is the doctor-blade tape casting technique. Glenn N. Howatt is regarded as the godfather of tape casting and established this processing method in 1947[1] and also filed the first patent in 1948[2]. A plentiful variety of electronic components like multilayer ceramic capacitors (MLCC), actuators (MLA), varistors (MLV) or tapes for low/high temperature cofired ceramics (LTCC, HTCC) can be manufactured.
Contents
Components of a tape caster
Tape casting machine
Tape casting machines are available in different scales. Usually big industrial companies have continuous tape casters with a length of several hundred meters. However, in academic research much smaller lab-scale tape casters are used which can range from half a meter to several meters in length.
Continuous as well as discontinuous tapes can be prepared with lab-scale tape casters. For continuous tapes, guide rollers and rollers with the carrier substrate are needed. If discontinuous tapes are produced, carrier substrate sheets can be used likewise.
The machines can be equipped with heating plates to keep the drying temperature constant. The ingredients of the slip need to be adjusted towards elevated temperatures to avoid rapid drying and bubbling. Solvents may evaporate much faster thereby degrading the green tape severly. It is recommended to use temperatures close to the room temperature.
Carrier substrate
Stainless steel belts as carrier substrates are most common in continuous manufacturing operations. It is economic and cost-effective. However, also Mylar, PTFE (Teflon), cellophane, silicone-coated polyester, and many other materials are suitable as well. Especially for lab-scales, Mylar sheets are easy to handle. If the tape caster The binder, solvent, and plasticizer system determines the interaction with the carrier material. The slip needs to wet the surface sufficiently and after drying the green tape needs to be peeled off well.
Reservoir
Doctor-blade
Other variables that come into play include reservoir depth, speed of carrier movement, viscosity of the slip, and shape of the doctor blade (to name just a few).
Drying chamber
Process of tape casting
Slip delivery
After mixing the slip system, air can be trapped within the slip. To remove remaining air bubbles and promote smooth and homogeneous green tapes without defects, a de-airing step is required. Putting the slip under vacuum will help to remove air. It needs to be noted that too high vacuum tends to let evaporate solvent. This will unbalance the weight ratios of the slip and change its rheological behavior. Subsequent to de airing the slip will be poured into the reservoir of the machine. Additional sieves can be used to prevent e.g. milling balls from falling into the reservoir. Before starting to cast the slip is supposed to be distributed in the reservoir.
Casting
The doctor-blade gap defines the wet thickness of the tape being cast. Either the substrate is stationary or the doctor-blade. The speed is supposed to be set in the range of 0.7 - 1 m/min.
Drying
Quality assessment
optical check, bubbles, orange peel, cracking, homogeneity, bendable, strechable, handable, homogeneous green sheet thickness, green density
References
- ↑ [1] Howatt, G.N., Breckenridge, R.G. and Brownlow, J.M. (1947), FABRICATION OF THIN CERAMIC SHEETS FOR CAPACITORS. Journal of the American Ceramic Society, 30: 237-242.
- ↑ [2] Howatt, G.N., Method of Producing High Dielectric High Insulation Ceramic Plates, U.S. Patent 2,582,993 (filed October 29, 1948).
- ↑ [3] Mistler, R.E. (1995), The principles of tape casting and tape casting applications. In: Terpstra, R.A., Pex, P.P.A.C., de Vries, A.H. (eds) Ceramic Processing. Springer, Dordrecht.
